Physicochemical Properties of Bis-GMA/TEGDMA Dental Resin Reinforced with Silanized Multi-Walled Carbon Nanotubes

Silicon - The multi-walled carbon nanotubes (CNTs) modified by different amount of silane coupling agents named 3-(methacryloxy)propyltrimethoxysilane (γ-MPS), were incorporated into dental...     

Microstructure and Mechanical Properties of Mg–RE–TM Cast Alloys Containing Long Period Stacking Ordered Phases: A Review

Casting magnesium alloys hold the greatest share of magnesium application products due to their short processing period, low cost and near net shape forming. Compared with conventional commercial magnesium alloys or other Mg–RE-based alloys, the novel Mg–RE–TM cast alloys with long period stacking ordered(LPSO) phases usually possess a higher strength and are promising candidates for aluminum alloy applications. Up to now, two ways: alloying design and casting process control(including subsequent heat treatments), have been predominantly employed to further improve the mechanical properties of these alloys. Alloying with other elements or ceramic particles could alter the solidifi cation pattern of alloys, change the morphology of LPSO phases and refi ne the microstructures. Diff erent casting techniques(conventional casting, rapidly solidifi cation, directional solidifi cation, etc.) introduce various microstructure characteristics, such as dendritic structure, nanocrystalline, metastable phase, anisotropy. Further heat treatments could activate the transformation of various LPSO structures and precipitation of diverse precipitates. All these evolutions exert great impacts on the mechanical properties of the LPSO-containing alloys. However, the underlying mechanisms still remain a subject of debate. Therefore, this review mainly provides the state of the art of the casting magnesium alloys research and the accompanying challenges and summarizes some topics that merit future investigation for developing high-performance Mg–RE–TM cast alloys.     

载气热提取法测定熔敷金属中扩散氢收集条件的探究

探究了GB/T 3965—2012《熔敷金属中扩散氢测定方法》中载气热提取法收集条件对测定扩散氢含量的影响,并与水银法进行了对比。研究结果表明,样本炉温设定为400℃,A型试块的内部温度大约在51 min时稳定在358℃左右,B型试块内部温度大约在27 min时稳定在391℃左右;载气热提取法电信号曲线收集结束点的电信号及斜率均接近0时获得的结果与水银法具有较好的一致性。     

羊场湾煤矿软岩底板炉渣混凝土加固技术

为提高软岩底板强度而供无轨胶轮车等大型车辆行驶，结合羊场湾煤矿16206机巷软岩底板地质条件，研究了炉渣混凝土底板加固技术，确定了合理的配比方案，并对机巷现场进行混凝土地坪铺设应用。研究与应用结果表明：炉渣混凝土底板强度可满足大型车辆连续运输所需，极大地提高了底板承载能力，防止底鼓，为长距离巷道实现连续运输提供了基础保障。     

城市污水厂剩余污泥对水中F-的吸附性能研究

利用城市污水处理厂的剩余污泥对水中F-进行吸附处理,通过污泥投加量、F-初始质量浓度、时间、pH等反应条件的研究,探讨除氟效果和影响因素。结果表明,室温下,污泥对F-的吸附在60 min后达到平衡;20 g/L的污泥投加量对10 mg/L含氟水的F-去除率可达83.1%;污泥可在3~10的较大pH范围内保持稳定的除氟效果。准二级动力学模型很好地拟合了污泥对F-的吸附行为,Langmuir和Freundlich模型均符合污泥对F-的吸附特性,热力学参数的计算表明该吸附过程是自发的放热反应。     

FDM 3D打印工艺参数对PLA制件力学性能的影响

采用五因素四水平正交试验设计,对16组不同工艺参数(打印层厚、填充密度、打印温度、填充速度、外壳厚度)的FDM 3D打印聚乳酸(PLA)制件力学性能进行了测试和结果分析,确定了影响PLA制件力学性能的主要因素,其中,外壳厚度对制件力学性能影响最为明显,打印温度影响最小,同时分析得到了在打印层厚0.15 mm,填充密度40%,打印温度210℃,填充速度60 mm/s,外壳厚度1.6 mm条件下可获得力学性能最佳的制件。最后对试验数据进行回归分析,拟合得到了FDM打印工艺参数与PLA制件力学性能指标的数学模型;通过对不同打印工艺参数的试样进行试验验证,表明该模型拟合误差小(5%以内),可靠性高,可用来对FDM 3D打印制件的加工提供参考。     

含天青石、石膏白云岩混合溶蚀特征研究

以亚洲第一长白云岩洞穴——贵州省遵义市绥阳双河洞地区的白云岩为研究对象,根据白云岩中石膏(或硬石膏)的存在可加速白云石溶解的理论,考虑双河洞洞穴中同时存在天青石(SrSO_4)与石膏(CaSO_4)岩层,溶解后形成混合溶液,可能会加速白云岩的溶蚀。白云岩在自然条件下常混有杂质,为了实验的准确性,直接采用白云石进行实验。在静态条件下进行白云石在含天青石和石膏的不同含量溶液中混合溶蚀的模拟实验,研究在常温酸性和中性条件下,双河洞地区的地下水以及地表水对白云岩溶蚀过程的影响。结果表明,根据地下水以及地表水中Ca/Sr比例不同以及pH值的不同,在离子强度以及同离子效应的影响下,Ca/Sr比例直接影响白云石的溶蚀率,且生成的过多沉淀吸附在白云石的溶蚀孔隙中,会导致实验反应减缓。该研究为解释绥阳双河洞白云岩洞穴的成因具有一定的指导意义。     

基于步冷试验的2.25Cr-1Mo-0.25V钢母材及焊缝回火脆化研究

对原始态、步冷态、脱脆态和脱脆步冷态2.25Cr-1Mo-0.25V钢母材及焊缝冲击试验结果进行分析,得到了母材和焊缝在不同状态下的韧脆转变温度vTr54.2和FATT以及脆化度ΔvTr54.2和ΔFATT。试验结果表明,步冷试验之后,母材发生较低程度脆化或脱脆现象,但是脆化度或脱脆度较低,表明母材具有良好的抗回火脆化性能;经脱脆试验后,母材和焊缝都发生较高程度的脱脆,表明材料的脆化主要是由于回火脆化引起的,脱脆试验使得材料的韧脆转变温度降低;脱脆步冷试验后,焊缝发生较高程度的脆化,焊缝对脱脆步冷试验的敏感性较高,脱脆步冷试验有效促进了焊缝的脆化。在相同脆化条件下,母材的脆化敏感性低于焊缝,焊缝更易发生脆化。     

β-Cypermethrin Alleviated the Inhibitory Effect of Medium from RAW 264.7 Cells on 3T3-L1 Cell Maturation into Adipocytes

Studies have elucidated that pyrethroids induce adipogenesis. It is also known that macrophages can affect the homeostasis of adipose tissue. However, whether and how the β-cypermethrin (β-CYP)-mediated inhibition of the macrophages affects adipogenesis remain unknown. To explore the effects of β-CYP on adipogenesis through modulating the function of macrophages, 3T3-L1 cells, a preadipocyte cell line, were exposed to culture medium from either RAW 264.7 cells, a macrophage cell line (RM), or β-CYP-treated RAW 264.7 cells (CRM). CRM decreased the inhibitory effects of RM treatment on cell proliferation and adipogenesis, as lipid accumulation, the CEBPA content, and Fasn and Acaca expression in 3T3-L1 cells were higher following CRM treatment than following RM treatment through the higher levels of the demethylated CEBPA promoter in 3T3-L1 cells. However, the medium from β-CYP- and N-acetyl-L-cysteine-cotreated RAW 264.7 cells (CNRM) partially restored the inhibitory effects of RAW 264.7 cells on 3T3-L1 cells that had been reduced by CRM, indicating that β-CYP might reduce the cytotoxicity and inhibitory effects of RAW 264.7 cells on the adipogenesis of 3T3-L1 cells through elevating ROS levels in RAW 264.7 cells. Moreover, exposure to β-CYP downregulated the TNF-α secretion in RAW 264.7 cells. In conclusion, these data demonstrated that β-CYP affected the function of RAW 264.7 cells, alleviating their inhibitory effects on adipogenesis and CEBPA demethylation in 3T3-L1 cells. β-CYP might achieve these effects through downregulating the secretion of TNF-α via elevating ROS levels in RAW 264.7 cells. Our experiments provide a new perspective on the obesogenic effect of pyrethroids.